The Real Ghostbusters S03 E07 Sticky Business

"Who you gonna call? Ghostbusters!"

The Ghostbusters release the Stay Puft Marshmallow Man from the containment unit to shoot a commercial in exchange for getting $50,000 for a children's hospital. However, during the process of letting Stay Puft out, a vicious manta ray-like phantom escapes in order to seek revenge against the Ghostbusters.