Durarara!! S00 E02 World at Peace

Yuuhei hosts a show searching for the loveliest couple in Ikebukuro, the winner of which gets to appear in one of his movies. Mikado and Anri go to the movies together, hoping to clear everything up between them, they end up being interviewed by Yuuhei. [This is Episode 25 of Season 1 Cour 2]